Anne Hathaway has had one of the most memorable style evolutions in Hollywood. In this episode of Clothes of Our Lives, the Oscar-winning actress sits down with ELLE to reflect on the looks that defined every era of her career—from the Calvin Klein dress she wore (and got sunburned in) to The Princess Diaries premiere to the Louis Vuitton look that marked Andy Sachs’s transformation in The Devil Wears Prada. Watch as our Summer issue cover star looks back on some of her most unforgettable fashion moments, including her first-ever Met Gala in Marc Jacobs, the Prada gown she wore to accept her Oscar for Les Misérables, and the famous leopard-print Valentino minidress that broke the internet.

Read the full cover story here.